InGoogle Chrome, both of these are different things.
By default, the Home button is hidden in Chrome, and there are no Startup pages configured.
However, this can be changed.

By default, this button is hidden.
Switch to the Appearance tab.Open Chromes appearance tweaks
unlock the Home button.
Toggle the slider in front of Show home button into theOnposition.

opt for custom web address radio button.
By default, Chrome opens the new-tab page.
you’re able to change this to any custom webpage, or multiple web pages.

If there are multiple web pages, then each webpage will open in a new tab.
However, you might still set a Homepage that will open every time you launch the surfing app.
Therefore, on Android and iOS devices, the Home page is the startup page.

Unfortunately, you might only set one home page on mobile devices.
Open Chromes tweaks.Open Chrome tweaks on Android
Open Homepage tweaks.Open Homepage tweaks
Enable Homepage (enabled by default).
This cannot be changed natively.

TheCustom New Tab URLChrome extension is exactly what its name says.
you’re free to configure it to open a specific web page when you open a new tab.
Open theCustom New Tab URLpage.

Click Add to Chrome.Add extension to Chrome
Click Add Extension.
The Custom New Tab URL will now be added to Chrome.
tap on the extension icon.

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source: www.itechtics.com