Windows Security is a Windows-native tool that protects your PC from malware and attacks a replacement forthird-party antivirus software.
An integral part of Windows Security isMicrosoft Defender system Guard.
That said, this feature needs to be installed and enabled manually on our computer.

Only when will you be able to provide additional security for your system and time spent online.
This utility works with Microsoft Office, Internet Explorer (deprecated), and Microsoft Edge.
In other words, any URL not mentioned in the whitelist will automatically run in an isolated environment.

How Application Guard works with Microsoft Edge. Source:Microsoft
This is due to the fact that the online session would be in standalone mode.
Therefore, all necessary security features ought to be enabled on enterprise devices.
Even though it is obvious why, connecting to an enterprise online grid gives access to any non-isolated devices.

Enable Microsoft Defender Application Guard using PowerShell
However, if they only use it for casual work, then the app Guard might be overkill.
This is a simple mechanism that Microsoft Defender system Guard uses to protect your devices and networks.
Once it is installed, you’re able to configure it to allow or restrict further functionality.

App and browser control in Windows Security
it’s possible for you to enable tool Guard using the Optional Features applet, or fromWindows PowerShell.
Now initiate the following cmdlet:
When asked to restart the computer, enter Y for Yes.
When the computer reboots, Microsoft Defender software Guard will be enabled.

Manage Application Guard from Group Policy settings
However, these features can be enabled on demand.
However, you’re free to allow certain access.
Alternatively, you could also manage Microsoft Defender app Guard from Group Policy tweaks.

New Application Guard window
This functionality can be useful for both enterprise users as well as individuals.
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source: www.itechtics.com